副教授 –唐生表
Email : shengbiaotang@cczu.edu.cn
教育經(jīng)歷:
2013/07-2016/06，北京大學(xué)-天津大學(xué) 聯(lián)合培養(yǎng)（博士），導(dǎo)師：葉新山教授
2011/09-2013/06，天津大學(xué)（碩士），導(dǎo)師：姜申德教授
工作經(jīng)歷：
2018/09-至今，常州大學(xué)
2016/06-2018/08，中科院上海有機(jī)化學(xué)研究所，博士后，合作導(dǎo)師：游書力研究員
研究方向:
不對(duì)稱合成，過渡金屬催化
教學(xué)科研項(xiàng)目:
(1) 國(guó)家自然科學(xué)基金委員會(huì), 面上項(xiàng)目, 21971026, 基于金屬卡賓的含氮雜環(huán)不對(duì)稱N-烷基化反應(yīng)研究, 2020-01-01 至 2023-12-31, 65萬(wàn)元, 在研, 參與（排名第二）。
(2) 國(guó)家自然科學(xué)基金委員會(huì), 青年科學(xué)基金項(xiàng)目, 21901022, 二烯化合物的區(qū)域及對(duì)映選擇性胺基化反應(yīng)研究, 2020-01-01 至 2022-12-31, 25萬(wàn)元, 在研, 主持。
近期發(fā)表論文
1) Tang, Shengbiao, * Zhang, Peng, Shao, Ying, Sun, Jiangtao, Enyne Diketones As New Classes Substrate in Asymmetric Nazarov Cyclization for Construction of Chiral Allene Cyclopentenone. Nat. Commun.2022, 13, 3146.Nat. Commun. 2022, 13, 3146.
2) Tang, Shengbiao, * Zhang, Peng, Wang, Changkai, Shao, Ying, Sun, Jiangtao, Iridium-catalyzed regio- and enantioselective allylic esterification of secondary allylic alcohols with carboxylic acids, Chem. Commun., 2021, 57, 11080-11083.
3) Shengbiao Tang,* Jianliang Yu, Ying Shao, Jiangtao Sun.* Scandium-catalyzed highly selective N2-alkylation of benzotriazoles with cyclohexanones，Org. Chem. Front., 2021, 8, 278-282.
4) Shengbiao Tang, Ziyong Li, Ying Shao, Jiangtao Sun.* Ir-Catalyzed Regiocontrolled Allylic Amination of Di-/Trienyl Allylic Alcohols with Secondary Amines, Org. Lett. 2019, 21, 18, 7228-7232.
5) Sheng-Biao Tang, Hang-Fei Tu, Xiao Zhang, and Shu-Li You.* Rhodium-Catalyzed Asymmetric Allylic Dearomatization of β-Naphthols: Enantioselective Control of Prochiral Nucleophiles. Org. Lett. 2019, 21, 6130?6134.
6) Sheng-Biao Tang, Xiao Zhang, Hang-Fei Tu, and Shu-Li You.* Regio- and Enantioselective Rhodium-Catalyzed Allylic Alkylation of Racemic Allylic Alcohols with 1,3-Diketones. J. Am. Chem. Soc. 2018, 140, 1137-1142.
7) Shengbiao Tang, Qiannan Zheng, De-Cai Xiong, Shende Jiang, Qin Li, and Xin-Shan Ye*. Stereocontrolled Synthesis of 2-Deoxy-C-glycopyranosyl Arenes Using Glycals and Aromatic Amines. Org. Lett. 2018, 20, 3079-3082.
8) Shengbiao Tang, De-Cai Xiong, Shende Jiang, and Xin-Shan Ye*. Nitro-polyols via Pyridine Promoted C=C Cleavage of 2-Nitroglycals. Application to the Synthesis of (-)-Hyacinthacine A1. Org. Lett. 2016, 18, 568–571.
9) Guangyang Xu, Ping Chen, Pei Liu, Shengbiao Tang, Xinhao, Zhang, Jiangtao Sun,* Access to N-Substituted 2-Pyridones by Catalytic Intermolecular Dearomatization and 1,4-Acyl Transfer. Angew. Chem. Int. Ed. 2019, 58, 1980-1984.
10) Kai Wang, Jianliang Yu, Ying Shao, Shengbiao Tang, Jiangtao Sun,* Forming All-Carbon Quaternary Stereocenters by Organocatalytic Aminomethylation: Concise Access to beta(2,2)-Amino Acids. Angew. Chem. Int. Ed. 2020, 59, 23516-23520.
11) Chemo- and Enantioselective Insertion of Furyl Carbene into the N-H Bond of 2-Pyridones. Wang K.; Liu, Z.; Xu, G.; Shao, Y.; Tang, S.; Chen, P.; Zhang, X.;* Sun, J.*. Angew. Chem. Int. Ed. 2021, 60, 16942-16946.
12) Construction of C-C Axial Chirality via Asymmetric Carbene Insertion into Arene C-H Bonds. Li, Z.; Chen, Y. Wang, C.; Xu, G.; Shao, Y.; Zhang, X.;* Tang, S.; Sun, J.* Angew. Chem. Int. Ed. 2021, 60, 25714-25718.
授權(quán)專利：
(1) 唐生表; 蘇家慧; 孫江濤 ; 一種苯并三氮唑及其衍生物高選擇性N2烷基化方法, 中國(guó), CN202010541148.1
(2) 唐生表; 張鵬; 孫江濤 ; 合成環(huán)外聯(lián)烯醇化合物的方法, 中國(guó), ZL202110305142.9
